The paper presents the results of studies on the changes in the PAHs concentration during pre-filtration and ultrafiltration (UF) processes. In the study, biologically treated wastewater (after denitrification and nitrification processes), discharged from the biological treatment plant and used in coke plant, was used. A gas chromatography-mass spectrometry (GC-MS) was used in order to qualify and quantify the PAHs. Sixteen PAHs listed by EPA were determined. The wastewater samples were collected three fold and initially characterized for the concentration of nitrate nitrogen, ammonium nitrogen, COD, TOC and pH. In the first step, wastewater was filtrated on the sand bed. Total concentration of 16 PAHs in the treated wastewater before initial filtration was in the range of 44.8‒53.5 mg/L. During the process the decrease in the concentration of the most studied hydrocarbons was observed. Concentration of PAHs after initial filtration ranged from 21.9 to 38.3 μg/L. After the initial filtration process the wastewater flew to the ultrafiltration module and then was separated on the membrane (type ZW-10). The total concentration of 16 PAHs in the process of ultrafiltration was in the range of 8.9‒19.3 mg/L. The efficiency of removal of PAHs from coke wastewater in the process of ultrafiltration equaled 66.6%. Taking into account the initial filtration, the total degree of removal of PAHs reached 85%. The obtained results indicate the possibility of using the ultrafiltration process with the initial filtration as additional process in the coke wastewater treatment.
The objective of the experiment was to evaluate the energy efficiency of the phytoremediation process, supported using energy crops. The scope of conducted work includes the preparation of a field experiment. During the evaluation, 2 factors were into consideration – total energy demand and total energy benefit. The case study, used as an origin of data, consists a 3-years field study, conducted with the use of 2 energy crops – Phalaris arundinacea L. and Brassica napus L. The area subjected to the experiment was polluted with polycyclic aromatic hydrocarbons (PAHs) and herbicides, classified as phenoxy acids (2, 4 D). The experimental design consisted of 4 groups of fields, divided according to the used plant species and type of treatment. For each energy crop, 2 types of fertilization strategies were used. Therefore the 1st and 3rd sets of fields were not treated with any soil amendment while the 2nd and 4th sets were fertilized with compost. The obtained data allowed to observe that the cultivation of P. arundinacea L. and B. napus L. allowed a positive energy balance of the process to be achieved. However, it should be noted, that the B. napus L. growth in the first vegetation season was not sufficient to fully compensate a total energy demand. Such a goal, in the mentioned case, was possible after the 2nd vegetation season. The collected results show also that the best energetic potential combined with the most effective soil remediation were obtained on the fields with the cultivation of P. arundinacea L. fertilized with compost. The number of biofuels, collected from the 1 ha of such fields, can reach a value equal even to12.76 Mg of coal equivalent.
Municipal waste management has been an area of special interest of the European Commission (EC) for many years. In 2018, the EC pointed out issues related to municipal waste management as an important element of the monitoring framework for the transition towards a circular economy (CE), which is currently a priority in the economic policy of the European Union (EU). In the presented monitoring framework, 10 CE indicators were identified, among which issues related to municipal waste appear directly in two areas of the CE – in the field of production and in the field of waste management, and indirectly – un two other areas – secondary raw materials, and competitiveness and innovation. The paper presents changes in the management of municipal waste in Poland in the context of the implementation of the CE assumptions, a discussion of the results of CE indicators in two areas of the CE monitoring framework in Poland (production and waste management), and a comparison of the results against other European countries.
In Poland, tasks related to the implementation of municipal waste management from July 1, 2013 are the responsibility of the municipality, which is obliged to ensure the conditions for the system of selective collection and collection of municipal waste from residents, as well as the construction, maintenance and operation of regional municipal waste treatment installations (RIPOK). The municipality is also committed to the proper management of municipal waste, in accordance with the European waste management hierarchy, whose overriding objective is to prevent waste formation and limiting its amount, then recycling and other forms of disposal, incineration and safe storage. The study analyzed changes in the value of two selected CE indicators, i.e. (1) the municipal waste generation indicator, in the area of production and (2) the municipal waste recycling indicator, in the area of waste management. For this purpose, statistical data of the Central Statistical Office (GUS) and Eurostat were used. Data has been presented since 2014, i.e. from the moment of initiating the need to move to the CE in the EU. In recent years, there has been an increase in the amount of municipal waste generated in Poland as well as in the EU. According to Eurostat, the amount of municipal waste generated per one inhabitant of Poland increased from 272 kg in 2014 to 315 kg in 2017. It should be noted that the average amount of municipal waste generated in Poland in 2017 was one of the lowest in EU, with a European average of 486 kg/person. Poland has achieved lower levels of municipal waste recycling (33.9%) than the European average (46%). The reason for Poland’s worse results in the recycling of municipal waste may be, among others, the lack of sufficiently developed waste processing infrastructure, operating in other countries such as Germany and Denmark, and definitely higher public awareness of the issue of municipal waste in developed countries. Municipal waste management in Poland faces a number of challenges in the implementation of GOZ, primarily in terms of achieving the recycling values imposed by the EC, up to a minimum of 55% by 2025.
The paper presents an application of Life Cycle Assessment (LCA) method for the environmental evaluation of the technologies for the fertilizers production. LCA has been used because it enables the most comprehensive identifi cation, documentation and quantifi cation of the potential impacts on the environment and the evaluation and comparison of all signifi cant environmental aspects. The main objective of the study was to assess and compare two technologies for the production of phosphorus (P) fertilizers coming from primary and secondary sources. In order to calculate the potential environmental impact the IMPACT 2002+ method was used. The fi rst part of the LCA included an inventory of all the materials used and emissions released by the system under investigation. In the following step, the inventory data were analyzed and aggregated in order to calculate one index representing the total environmental burden. In the scenario 1, fertilizers were produced with use of an integrated technology for the phosphorus recovery from sewage sludge ash (SSA) and P fertilizer production. Samples of SSA collected from two Polish mono-incineration plants were evaluated (Scenario 1a and Scenario 1b). In the scenario 2, P-based fertilizer (reference fertilizer – triple superphosphate) was produced from primary sources – phosphate rock.
The results of the LCA showed that both processes contribute to a potential environmental impact. The overall results showed that the production process of P-based fertilizer aff ects the environment primarily through the use of the P raw materials. The specifi c results showed that the highest impact on the environment was obtained for the Scenario 2 (1.94899 Pt). Scenario 1a and 1b showed the environmental benefi ts associated with the avoiding of SSA storage and its emissions, reaching -1.3475 Pt and -3.82062 Pt, respectively. Comparing results of LCA of P-based fertilizer production from diff erent waste streams, it was indicated that the better environmental performance was achieved in the scenario 1b, in which SSA had the higher content of P (52.5%) in the precipitate. In this case the lower amount of the energy and materials, including phosphoric acid, was needed for the production of fertilizer, calculated as 1 Mg P2O5. The results of the LCA may play a strategic role for the decision-makers in the aspect of searching and selection of the production and recovery technologies. By the environmental evaluation of diff erent alternatives of P-based fertilizers it is possible to recognize and implement the most sustainable solutions.