Trichloroethene (TCE) and tetrachloroethene (PCE) are chemical compounds which pose a serious threat for human health. Their specific properties make it possible that these substances may linger in soil and water for many years. These are the reasons why wells with water designed for drinking purposes have been subject of monitoring since 2006. This paper presents the results of monitoring research conducted in the soil-water environment within the framework in third phase of an ecological audit of land. The ecological audit of land made it possible to identify the cause and degree of the degradation, and helped formulate rationale for remedy decisions pertaining to the land (remediation/reclamation). The objective of the paper was to determine the pollution status of the soil-water environment and, subsequently, monitor (in years 2008-2010) the contents of the hazardous substances, namely trichloroethene and tetrachloroethene, within the area of the potential impact of metallurgical plant located in borders of the Main Underground Water Reservoir Wierzbica-Ostrowiec (GZWP 420) in in voivodeship Świętokrzyskie.
A representative group of hydrophilic fungi from the genus Trichoderma isolated from lignocellulose composts with varying degrees of maturity was analyzed for their ability to biodegrade a harmful anthraquinone dye, i.e. Remazol Brilliant Blue R (RBBR). In RBBR-containing post-culture liquids, there were determined the degree of RBBR decolorization, horseradish peroxidase-like, superoxide dismutase-like, and xylanase activities, and the concentrations of low-molecular phenolic compounds. The study results demonstrated that Trichoderma asperellum, T. harzianum, and T. lixii strains isolated from compost containing larger amounts of easily available lignocellulose fractions, i.e. grasses, exhibit higher RBBR decolorization effi ciency ranging from 0.3 to 62% than T. citrinoviride strains isolated from compost II, which contained greater quantities of hardly degradable lignocellulose. The decolorization of remazol blue R by the investigated Trichoderma strains intensified signifi cantly with the increase in peroxidase activity and it was correlated with a decline in the content of low-molecular phenolic compounds. The dynamics of changes in the horseradish peroxidase-like, superoxide dismutase, and xylanase activities in the aqueous post-culture liquids of the investigated fungal strains depended largely on the duration of the culture. Given their ability to adapt to water environments, e.g. wastewater, and to decolorize and detoxify the RBBR anthraquinone dye, Trichoderma fungi can be used for bioremediation of such environments.
The Panorama Point Beds represent a subfacies of the Early to Middle Permian Radok Conglomerate, which is the oldest known sedimentary unit in the Prince Charles Mountains, MacRobertson Land, East Antarctica. This unit records clastic sedimentation in fresh−water depositional system during the early stages of development of the Lambert Graben, a major structural valley surrounded by crystalline highlands in the southern part of Gondwana. It contains common siderite precipitated through early diagenetic processes in the swamp, stagnant water, and stream−flow environments. There are two types of siderite in the Panorama Point Beds: (1) disseminated cement that occurs throughout the sedimentary suc− cession; and (2) concretions that occur at recurrent horizons in fine−grained sediments. The cement is composed of Fe−depleted siderite (less than 90mol%FeCO3)with an elevated con− tent of magnesium, and trace and rare earth elements. It has negative δ13CVPDB values (−4.5 to −1.5‰). The concretions are dominated by Fe−rich siderite (more than 90mol% FeCO3),with positive δ13CVPDB values (+1 to +8‰). There are no noticeable differences in the oxygen (δ18OVPDB between −20 and −15‰) and strontium (δ87Sr/86Sr between 0.7271 and 0.7281) iso− topic compositions between the siderite types. The cement and concretions developed in the nearsurface to subsurface environment dominated by suboxic and anoxic methanic degrada− tion of organic matter, respectively. The common presence of siderite in the Panorama Point Beds suggests that fresh−water environments of the Lambert Graben were covered by vegetation, starting from the early history of its development in the Early Permian.