Applied sciences

Chemical and Process Engineering: New Frontiers

Content

Chemical and Process Engineering | 2013 | No 3 September

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Abstract

The mathematical model of postproduction suspension concentration by microfiltration has been developed. This model describes a process conducted in a batch system with membrane washing by reverse flow of permeate. The model considerations concern filtration pseudocycles consisting of the filtration period and the membrane washing period. The balances of continuous phase volume, dispersed phase mass and energy, for each period of pseudocycle respectively, have been presented.

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Authors and Affiliations

Zbigniew Szwast
Maciej Szwast
Marian Grądkowski
Wojciech Piątkiewicz
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Abstract

Electroflotation is used in the water treatment industry for the recovery of suspended particles. In this study the bubble formation and release of hydrogen bubbles generated electrolytically from a platinum cathode was investigated. Previously, it was found that both the growth rate and detachment diameter increased with increasing wire diameter. Conversely, current density had little effect on the released bubble size. It was also found that the detached bubbles rapidly increased in volume as they rose through the liquid as a result of decreasing hydrostatic pressure and high levels of dissolved hydrogen gas in the surrounding liquid. The experimental system was computationally modelled using a Lagrangian-Eulerian Discrete Particle approach. It was revealed that desorption of gaseous solutes from the electrolyte solution, other than hydrogen, may have a significant impact on the diameter variation of the formed bubbles. The simulation confirmed that liquid circulation, either forced or induced by the rising bubble plume, influences both the hydrogen supersaturation (concentration) in the neighbourhood of the electrode and the size of the resulting bubbles.

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Authors and Affiliations

Shahjahan K. A. Sarkar
Piotr M. Machniewski
Geoffrey M. Evans
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Abstract

The paper presents results of coal behaviour during combustion in oxy-fuel atmosphere. The experiment was performed using 3 meter long Entrained Flow Reactor and 1 meter long Drop Tube Reactor. Three hard coals and two lignites were analysed in order to investigate NOx, SO2 emission and fly ash burnout. The measurements were performed along and at the outlet of a combustion chamber for one- and two - stage combustion. In the second stage of the experiment, kinetic parameters for nitrogen evolution during combustion in oxy - fuel and air were calculated and the division of nitrogen into the volatile matter and the char was measured. The conducted experiment showed that emissions in oxy - fuel are lower than those in air.

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Authors and Affiliations

Wojciech Moroń
Krzysztof Czajka
Wiesław Ferens
Konrad Babul
Arkadiusz Szydełko
Wiesław Rybak
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Abstract

A numerical algorithm is presented for the filling process of a cylindrical column with equilateral cylinders. The process is based on simplified mechanics - the elements are added one by one until the mechanical equilibrium is reached. The final structure is examined with respect to the global and local porosity distribution. Oscillating radial porosity profile is obtained in accordance with experimental data.

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Authors and Affiliations

Maciej Marek
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Abstract

A process capable of NOx control by ozone injection gained wide attention as a possible alternative to proven post combustion technologies such as selective catalytic (and non-catalytic) reduction. The purpose of the work was to develop a numerical model of NO oxidation with O3 that would be capable of providing guidelines for process optimisation during different design stages. A Computational Fluid Dynamics code was used to simulate turbulent reacting flow. In order to reduce computation expense a 11-step global NO - O3 reaction mechanism was implemented into the code. Model performance was verified by the experiment in a tubular flow reactor for two injection nozzle configurations and for two O3/NO ratios of molar fluxe. The objective of this work was to estimate the applicability of a simplified homogeneous reaction mechanism in reactive turbulent flow simulation. Quantitative conformity was not completely satisfying for all examined cases, but the final effect of NO oxidation was predicted correctly at the reactor outlet.

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Authors and Affiliations

Norbert J. Modliński
Włodzimierz K. Kordylewski
Maciej P. Jakubiak
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Abstract

In this study, β-galactosidase enzyme from Kluyveromyces fragilis was immobilised on a commercial polyethersulfone membrane surface, 10 kDa cut-off. An integrated process, concerning the simultaneous hydrolysis-ultrafiltration of whey lactose was studied and working conditions have been fixed at 55°C and pH 6.9, the same conditions that are used for the industrial process of protein concentration. For the immobilisation, best results were obtained using 5% (v/v) of glutaraldehyde solution and 0.03 M galactose; the total activity recovery coefficient (TARC) was 44.2%. The amount of immobilised enzyme was 12.49 mg with a total activity of 86.3 LAU at 37°C, using 5% (w/v) lactose solution in phosphate buffer (100 mM pH 6.9).

The stability of the immobilised enzyme was approximately 585 fold higher in comparison with the stability of free enzyme. Multipoint covalent immobilisation improves the stability of the enzyme, thereby enhancing the decision to use the membrane as a filtering element and support for the enzyme immobilisation.

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Authors and Affiliations

Silvina A. Regenhardt
Enrique J. Mammarella
Amelia C. Rubiolo
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Abstract

Binary vapour-liquid equilibrium of thymoquinone and carbon dioxide at the isothermal conditions was carried out at temperature 323.15 K and pressures from 6 to 10 MPa. The experimental data were fitted to the Soave-Redlich-Kwong equation of state. Results could be used for selection of process parameters in separation of volatiles from raw oil or for evaluation of existing separation technologies.

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Authors and Affiliations

Karina Gurgenova
Rafał Bogeł-Łukasik
Paweł Wawrzyniak
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Abstract

The paper presents the results of the mechanical, electrical, CCSEM and XRD measurements of hard coal, conducted in simulated conditions of sintering in atmospheres of O2/CO2,. The changes of the coal ash resistivity are correlated with the content of the oxides and with the sintering temperature determined by the mechanical test and Leitz method. The SEM-EDS analysis was conducted for deposits on the probe. The changes of the measured ash samples, observed during sintering process in O2/CO2 atmosphere, were discussed in the ash microstructure point of view.

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Authors and Affiliations

Dorota Nowak-Woźny
Wojciech Moroń
Bartosz Urbanek
Wiesław Rybak
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Abstract

In this study, the process of membrane cleaning by supercritical fluid extraction was investigated. Polypropylene microfiltration membranes, contaminated with oils, were treated in a batch process with a supercritical fluid (SCF). As extractant, pure supercritical carbon dioxide or supercritical carbon dioxide with admixtures of methanol, ethanol and isopropanol were used. Single-stage and multi-stage extraction was carried out and process efficiency was determined. The obtained results showed that addition of organic solvents significantly enhances the cleaning performance, which increases with increase of organic solvent concentration and decreases with increasing temperature. All three solvents showed a comparable effect of efficiency enhancement. The results confirmed that supercritical fluid extraction can be applied for polypropylene membrane cleaning.

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Authors and Affiliations

Jan Krzysztoforski
Andrzej Krasiński
Marek Henczka
Wojciech Piątkiewicz
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Abstract

Samples of active coke, fresh and spent after cleaning flue gases from communal waste incinerators, were studied. The outer layers of both coke particles were separately removed by comminution mechanism in a spouted bed. Analyses included density, mercury porosimetry and adsorption. The remaining cores were examined to determine the degree of consumption of coke by adsorption of hazardous emissions (SO2, HCl, heavy metals) through its bed. The differences in contamination levels within the porous structure of the particles were estimated. The study demonstrated the effectiveness of active coke in the cleaning of flue gases.

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Authors and Affiliations

Bronisław Buczek

Instructions for authors

All manuscripts submitted for publication in Chemical and Process Engineering: New Frontiers must comprise a description of original research that has neither been published nor submitted for publication elsewhere.

The content, aim and scope of the proposals have to comply with the main topics of the journal, i.e. discuss at least one of the four main areas, namely:
• New Advanced (Nano) Materials
• Environment & Water Processing (including circular economy)
• Biochemical & Biomedical Engineering (including pharmaceuticals)
• Climate & Energy (including energy conversion & storage, electrification, decarbonization)

Chemical and Process Engineering: New Frontiers publishes: i) experimental and theoretical research papers, ii) short communications, iii) critical reviews, and iv) perspective articles. Each publication form is peer-reviewed by at least two independent referees.

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Manuscripts are submitted for publication via Editorial System. When writing a manuscript, you may choose to submit it as a single Word file to be used in the refereeing process. The manuscript needs to be written in a clear way. The minimum requirements are:
• Please use clear fonts, at least 12 points large, with at least 1.5-line spacing.
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• Use Simple Past to talk about your experiment and your results as they were finished before you wrote the paper. Use Simple Past to describe what you did.
Example: Two samples were taken. Temperature increased to 200K at the end of the process.
• Use Simple Present to refer to figures and tables.
Example: Table 2 shows nitrogen concentration changes in the process.
• Use Simple Present to talk about your conclusions. You move here from describing your results to stating what is generally true.
Example: The process is caused by changes of nitrogen concentration.
• Capitalise words like ‘Table 2’, ‘Equation 11’.
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Articles
Charpentier J. C., McKenna T. F., 2004. Managing complex systems: some trends for the future of chemical and process engineering. Chem. Eng. Sci., 59, 1617-1640. DOI: 10.1016/j.ces.2004.01.044.
Information from books (we suggest adding the page numbers where the quoted information can be found)
Bird R. B., Stewart W.E., Lightfood E.N., 2002. Transport Phenomena. 2nd edition, Wiley, New York, 415-421.
Chapters in books
Hanjalić K., Jakirlić S., 2002. Second-moment turbulence closure modelling, In: Launder B.E., Sandham N.D. (Eds.), Closure strategies for turbulent and transitional flows. Cambridge University Press, Cambridge, 47-101.
Conferences
ten Cate A., Bermingham S.K., Derksen J.J., Kramer H.M.J., 2000. Compartmental modeling of an 1100L DTB crystallizer based on Large Eddy flow simulation. 10th European Conference on Mixing. Delft, the Netherlands, 2-5 July 2000, 255-264.



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Peer-review procedure
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Authors are kindly requested to include a list of 4 potential reviewers for their manuscript, providing complete contact information. The suggested reviewers should not reside in the same country as the corresponding author and remain subject to the Editors' discretion when assigning manuscripts for review.

The entire review process is conducted within the Editorial System.

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