@ARTICLE{Hu_Xiangyang_Simultaneous_2022, author={Hu, Xiangyang and Wang, Bao and Yan, Gengsheng and Ge, Bizhou}, volume={48}, number={3}, pages={37-47}, journal={Archives of Environmental Protection}, howpublished={online}, year={2022}, publisher={Polish Academy of Sciences}, abstract={An organobentonite modified with an amphoteric surfactant, tallow dihydroxyethyl betaine (TDHEB), was used as an adsorbent to simultaneously remove Cu(II) and phenol from wastewater. The characteristic of the organobentonite (named TDHEB-bentonite) was analyzed by X-ray diffraction, Fourier-transform infrared spectra and nitrogen adsorption-desorption isotherm. Batch tests were conducted to evaluate the adsorption capacities of TDHEB-bentonite for the two contaminants. Experiment results demonstrated that the adsorption of both contaminants is highly pH-dependent under acidic conditions. TDHEB-bentonite had about 2.0 and 5.0 times higher adsorption capacity toward Cu(II) and phenol, respectively, relative to the corresponding raw Na-bentonite. Adsorption isotherm data showed that the adsorption processes of both contaminants were well described by Freundlich model. Kinetic experiment demonstrated that both contaminants adsorption processes correlated well with pseudo-second-order model. Cu(II) had a negative impact on phenol adsorption, but not vice versa. Cu(II) was removed mainly through chelating with the organic groups (-CH2CH2OH and -COO-) of TDHEB. Otherwise, partition into the organic phase derived from the adsorbed surfactant was the primarily mechanism for phenol removal. Overall, TDHEB-bentonite was a promising adsorbent for removing Cu(II) and phenol simultaneously from wastewater.}, type={Article}, title={Simultaneous removal of phenol and Cu(II) from wastewater by tallow dihydroxyethyl betaine modified bentonite}, URL={http://ochroma.man.poznan.pl/Content/124074/PDF/Archives%20vol%2048_3pp37_47.pdf}, doi={10.24425/aep.2022.142688}, keywords={simultaneous adsorption;, bentonite;, tallow dihydroxyethyl betaine;, Cu(II);, phenol;}, }