The aim of the research conducted in a 2-year pot experiment in an unheated plastic tunnel was to determine suitability of Miscanthus × giganteus for phytoextraction of nickel from soil as well as to assess tolerance of this species on increasing concentrations of this metal in soil. Pots were filled with mineral soil (sand) and a mixture of soil with high-moor peat and three levels of nickel were introduced, i.e. 75 mg dm-3, 150 mg dm-3 and 600 mg dm-3 and the control combinations used substrates without the addition of nickel. Nickel was introduced only in the first year of the experiment in the form of nickel sulfate (NiSO4 · 6H2O). Miscanthus × giganteus accumulated a considerable amount of nickel in biomass. Miscanthus × giganteus growing in contaminated mineral soil turned out to be a species tolerant to high nickel concentrations
This paper presents the results of research of Ni/diamond composite coatings produced by electrochemical reduction method. Research was focused on composite coatings with nickel matrix and diamond as a disperse phase and for comparison purposes on nanocrystalline nickel coatings. Ni/diamond composite coatings were produced in baths with different content of nanodiamond powder. The structures of the dispersed phase and the composite coatings were analysed by using X-ray diffraction, scanning electron microscopy and light microscopy. Measurements of selected properties of the coatings were performed, including roughness, microhardness, adhesion and abrasive wear resistance. The research results indicate that the produced coatings have a compact structure and good adherence to steel substrate. Moreover, nanocrystalline Ni/diamond composite coatings exhibit greater hardness and reduced abrasive wear resistance compared to nanocrystalline nickel coatings.
Serpentine soils from 16 sample points in Serbia as well as the roots and shoots of eight Brassicaceae family species: Aethionema saxatile, Alyssum montanum, Alyssum repens, Cardamine plumieri, Erysimum linariifolium, Erysimum carniolicum, Isatis tinctoria, Rorippa lippizensis, were analyzed with regard to their concentrations of P, K, Fe, Ca, Mg, Ni, Zn, Mn, Cu, Cr, Cd, and Pb. Most of the soil samples were typical of ultramafic sites with low concentrations of P, K and Ca and high concentrations of Mg, Fe, Ni and Zn. Ca/Mg ratio was <1 in most soil samples and Brassicaceae plants. Only in A. montanum, A. repens, E. linariifolium and R. lippizensis was the Ca/Mg ratio >1. The levels of P, K, Fe and Zn were high, Mn and Cu occurred in low amounts, whereas Cr, Cd, Co and Pb were only traceable. In the roots and shoots of A. montanum and A. repens the measured concentrations of Ni were 657 mg kg-1 and 676 mg kg-1 respectively, which is the first instance that such high concentrations of Ni were detected in these two species.
The paper presents the adaptation of the modified pulse method for investigating temperature characteristics of thermal diffusivity in the vicinity of the second-order phase transition points. The principle of the adaptation consists in the modified in relation to the original method, development of the characteristics of temperature changes between boundary surfaces of a flat-parallel specimen after the laser shot onto its front surface. The application of this adaptation was illustrated with investigation into thermal diffusivity of nickel (99.9% wt) in the temperature range of 20-380◦C. In all cases the measurement error was less than 3%, and the averaging interval for the measured values of thermal diffusivity was not greater than 1.2 K.
FeCl3 bearing etching solution is mainly used for etching of metals used in shadow masks, PCBs and so on. Due course of Invar alloy etching process the FeCl3 bearing etching solution get contaminated with Ni2+ which affect adversely the etching efficiency. Hence, FeCl3 bearing etching solution discarded after several cycle of operation causes an environmental and economic problem. To address both the issues the etching solution was purified through solvent extraction and remained Ni2+ recovered by wet chemical reduction using hydrazine. For optimum Fe3+ extraction efficiency, various extraction parameter were optimized and size and morphology of the recovered pure Ni powder was analyzed. The reported process is a simple process to purify and recover Ni from industry etching solution.
This work presents the results of a study whose aim was to determine the influence of algal blooms on precipitation of heavy metals. The scope of the study covered culture of a mixed population made up of Scenedesmus and Pseudokirchneriella algae in experimental conditions and initiating a metal biosorption process with the use of culture biomass by administering ions of Zn(II) and Ni(II). The process was controlled by assessing the level of biosorption of metals entered at a one-off basis in the form of Zn(II) and Ni(II) salts or in the form of mixture of both ions, in comparison to the control sample, at different exposure times (2 hours and 24 hours). The presence of metals was determined both in the biomass and in the culture medium. The presented results of the study confirm the effectiveness of Chlorophyta in the process of zinc and nickel biosorption. A phenomenon of competitiveness between the metals was observed when they were administered at the same time.
Paper presents the results of evaluation of heat resistance and specific heat capacity of MAR-M-200, MAR-M-247 and Rene 80 nickel
superalloys. Heat resistance was evaluated using cyclic method. Every cycle included heating in 1100°C for 23 hours and cooling for 1
hour in air. Microstructure of the scale was observed using electron microscope. Specific heat capacity was measured using DSC
calorimeter. It was found that under conditions of cyclically changing temperature alloy MAR-M-247 exhibits highest heat resistance.
Formed oxide scale is heterophasic mixture of alloying elements, under which an internal oxidation zone was present. MAR-M-200 alloy
has higher specific heat capacity compared to MAR-M-247. For tested alloys in the temperature range from 550°C to 800°C precipitation
processes (γ′, γ′′) are probably occurring, resulting in a sudden increase in the observed heat capacity.
Superalloys show a good combination of mechanical strength and resistance to surface degradation under the influence of chemically
active environments at high temperature. They are characterized by very high heat and creep resistance. Their main application is in gas
turbines, chemical industry, and in all those cases where resistance to creep and the aggressive corrosion environment is required. Modern
jet engines could never come into use if not for progress in the development of superalloys. Superalloys are based on iron, nickel and
cobalt. The most common and the most interesting group includes superalloys based on nickel. They carry loads at temperatures well in
excess of the eighty percent of the melting point. This group includes the H282 alloy, whose nominal chemical composition is as follows
(wt%): Ni - base, Fe - max. 1.5%, Al - 1.5% Ti - 2.1%, C - 0.06% Co - 10% Cr - 20% Mo - 8.5%. This study shows the results of thermal
analysis of the H282 alloy performed on a cast step block with different wall thickness. Using the results of measurements, changes in the
temperature of H282 alloy during its solidification were determined, and the relationship dT / dt = f (t) was derived. The results of the
measurements taken at different points in the cast step block allowed identifying a number of thermal characteristics of the investigated
alloy and linking the size of the dendrites formed in a metal matrix (DAS) with the thermal effect of solidification. It was found that the
time of solidification prolonged from less than ome minute at 10 mm wall thickness to over seven minutes at the wall thickness of 44 mm
doubled the value of DAS.
Nickel alloys belong to the group of most resistant materials when used under the extreme operating conditions, including chemically
aggressive environment, high temperature, and high loads applied over a long period of time. Although in the global technology market
one can find several standard cast nickel alloys, the vast majority of components operating in machines and equipment are made from
alloys processed by the costly metalworking operations. Analysis of the available literature and own studies have shown that the use of
casting technology in the manufacture of components from nickel alloys poses a lot of difficulty. This is due to the adverse technological
properties of these alloys, like poor fluidity, high casting shrinkage, and above all, high reactivity of liquid metal with the atmospheric air
over the bath and with the ceramic material of both the crucible and foundry mold. The scale of these problems increases with the expected
growth of performance properties which these alloys should offer to the user.
This article presents the results of studies of physico-chemical interactions that occur between theH282alloy melt and selected refractory
ceramic materials commonly used in foundry. Own methodology for conducting micro-melts on a laboratory scale was elaborated and
discussed. The results obtained have revealed that the alumina-based ceramics exhibits greater reactivity in contact with the H282 alloy
melt than the materials based on zirconium compounds. In the conducted experiments, the ceramic materials based on zirconium silicate
have proved to be a much better choice than the zirconia-silica mixture. Regardless of the type of the ceramic materials used, the time and
temperature of their contact with the nickel alloy melt should always be limited to an absolutely necessary minimum required by the
technological regime.
The paper presents the results of studies to determine the effect of complex surface and bulk modification and double filtration during mould pouring on the stereological parameters of macrostructure and mechanical properties of castings made from the post-production waste IN-713C and the MAR-247 nickel alloys. The evaluation covered the number of grains per 1mm2 of the sample surface area, the average area of grains and the shape index, hardness HB, tensile strength and resistance to high temperature creep. The results indicate the possibility of controlling the stereological parameters of macrostructure through application of several variants of the modification, controlling in this way also different low- and high-temperature properties. The positive effect of double filtration of the alloy during mould pouring on the metallurgical quality and mechanical properties of castings has also been emphasized.
The paper presents results of research on cobalt and nickel ions removal from monocomponent solutions
using Purolite ion exchange resins. It has been shown that C 160 ion exchange resin has the best
sorption properties for both ions (Qe – 72.5 mg Co/g and 88.2 mg Ni/g). Regeneration process of this
ion exchanger has high efficiency, achieving about 93% for cobalt ions and about 84% in case of nickel
ions. It has been shown that the use of ion exchange method with suitable ion exchange resins guarantees
effective removal of cobalt and nickel ions from solutions with very high concentrations corresponding
to contents of these metals in industrial wastewaters (e.g. galvanic). In case of C 160 ion exchange resin,
after the sorption process is carried out in one 50 minute cycle, the cobalt concentration decreased from
about 30 000 mg/L to about 9 500 mg/L (approx. 68%), whereas nickel concentration reached about
6 300 mg/L (approx. 79%). Studied chelating resins don’t have such high sorption capacities. In their
case, it is required to convert cobalt and nickel ions into complex forms. The kinetics of studied processes
were described by pseudo-second order equations.
The paper presents the results of studies of hybrid composite layers Ni/Al2O3/Cgraphite produced by the electrodeposition method. Three variants of hybrid composite layers were prepared in electrolyte solutions with the same amounts of each dispersion phases which were equal to 0.25; 0.50 and 0.75 g/dm3. The structure of Ni/Al2O3/Cgraphite layers as well as the Al2O3 and graphite powders, which were used as dispersion phases was investigated. The results of morphology and surface topography of produced layers are presented. The modulus of elasticity and microhardness of the material of produced layers were determined by DSI method. Tribological and corrosion resistance tests of produced layers were carried out. Realized studies have shown that the material of the produced layers is characterized by a nanocrystalline structure. Incorporation of dispersion phases into the nickiel matrix increases the degree of surface development of layers. Ni/Al2O3/Cgraphite layers are characterized by high hardness and abrasion resistance by friction, furthermore, they provide good corrosion protection for the substrate material.