Abstract
The paper presents empirical relationships for the determination ofyield and true density ofchars produced within the temperature range of coal plasticity. At this stage of carbonisation process, loose coal grains are transformed into agglomerated coke structure. The course of this transformation determines the properties of produced coke. Mass and true density changes ofcarbonised coal at this stage ofcarbonisation influence volume changes ofsolid material and, as a result, the porosity of obtained coal. Therefore the formulae concerning mass and volume changes within the temperature range ofcoal plasticity constitute an important element ofthe model ofcoking process. The first part of the paper contains the formulae referring to the mass and true density changes of mineral matter in carbonised coals. These formulae have been derived on the basis of the model of mineral components behaviour during carbonisation. The next part of the paper presents the formulae concerning the mass changes of organic matter in coal within the temperature range of its plasticity. On deriving the formulae it was assumed that, within the temperature range of plasticity, the organic matter could divided into two types, i.e. the organic matter of raw coal and the organic matter of resulting semi-coke. Moreover, the conversion of coal into semi-coke has been described by means of the Clp(t)- function. The parameters of this function have been determined on the basis of experimental data. The final part of the paper contains the formulae for calculation of yield and true density of chars produced within the temperature range of coal plasticity. The formulae presented in this paper arc based on laboratory research carried out under conditions similar to those in coking chamber (the rate of heating, the composition and pressure of gaseous atmosphere, the bulk density and the size of coal grains). For this reason the presented formulae can be used in the modelling of coking process on commercial scale.
Go to article